IB Diploma Programme ChemistryFirst assessment 2025SL + HL
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Models of the particulate nature of matter

Five sub-topics, from the kinetic model of the three states through to the ideal gas equation. The thread running through all of them: matter is particles, and everything measurable is a consequence of how many there are and how fast they move.

S1.1 · S1.2

Introduction to the particulate nature of matter · The nuclear atom

notes4 animations2 models5 h
S1.3

Electron configurations

notes12 animations2 models6 h
S1.4

Counting particles by mass: the mole

notes10 animations2 models7 h
S1.5

Ideal gases

notes3 animations2 models3 h

Models of bonding and structure

Ionic, covalent and metallic are three models, not three boxes. The last sub-topic makes that explicit: real substances sit on a continuum, and the position on it predicts the properties.

S2.1

The ionic model

notes4 animations2 models
S2.2 Part A

The covalent model — SL core

notes21 animations9 models
S2.2 Part B

The covalent model — additional higher level

notes6 animations1 model
S2.3

The metallic model

notes3 animations2 models
S2.4

From models to materials

notes5 animations2 models

Classification of matter

Two classification systems: the periodic table for elements, functional groups for organic compounds. Both exist because position predicts behaviour — that is the whole claim, and both sub-topics test it.

S3.1

The periodic table: classification of elements

notes1 model11 h
S3.2 Part A

Functional groups: classification of organic compounds — SL core

notes9 h
S3.2 Part B

Stereochemistry and spectroscopic identification — AHL

notes1 model11 h

What drives chemical reactions?

Enthalpy alone answers this at standard level and gets it wrong often enough that higher level has to add entropy. The four sub-topics build in that order: energy in and out, energy accounted for around a cycle, energy from fuels, and then the quantity that actually decides.

R1.1

Measuring enthalpy changes

notes1 model5 h
R1.2

Energy cycles in reactions

notes1 model8 h
R1.3

Energy from fuels

notes4 h
R1.4

Entropy and spontaneity

notes1 model5 h

How much, how fast and how far?

Three separate questions that students routinely merge. Amount is fixed by the equation, rate by the energy barrier, and extent by the equilibrium constant — and none of the three predicts the others.

R2.1

How much? The amount of chemical change

notes1 model
R2.2

How fast? The rate of chemical change

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R2.3

How far? The extent of chemical change

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What are the mechanisms of chemical change?

Four mechanisms classified by what happens to a pair of electrons: transferred as a proton, transferred as an electron, shared one each, or supplied entirely by one partner.

R3.1

Proton transfer reactions

notes3 models
R3.2

Electron transfer reactions

notes4 models
R3.3 · R3.4

Electron sharing and electron-pair sharing reactions

notes1 model